Comparative evaluation of a reagent based on various сatalysts used for wastewater treatment
https://doi.org/10.32786/2071-9485-2023-04-50
Abstract
A comparative assessment of various catalysts for ferrite formation during wastewater treatment is considered. Obtaining optimal parameters of time and volume of a substance to reduce the concentration of chemical elements to the maximum permissible concentration.
Introduction. The ecological situation in our country at this point in time is considered unsatisfactory. Air pollution occurs due to large amounts of emissions from industrial plants; rivers and lakes are polluted by emissions of industrial, livestock and domestic wastewater. A known reagent method for wastewater treatment is ferritization or the formation of oxypheres. This method is well used for industrial plants such as paint and varnish, woodworking, metal production, etc. There is ferrite formation on several catalysts, such as ferrous sulfate, copper sulfate, so there is a need to conduct an experiment to study various catalysts to determine the best one for the absorption of chemical impurities.
Object. The object of the study is highly contaminated wastewater.
Materials and methods. A chemical analytical analysis of the wastewater under study was performed to determine the concentration of heavy metals. Next, experiments were carried out with various catalysts in laboratory conditions by settling at different periods of time and the volume of ferrite formation suspension.
Results and conclusions. The best result was shown by a catalyst in the form of iron sulfate, in which the ferrite formation reaction proceeded faster than with aluminum oxide and copper sulfate. The settling was carried out at intervals of 0.3 to 4 hours, the volume of the suspension used was from 20 to 50 ml. With these parameters, it was found that the contact time of the catalyst with the wastewater under study was 2 hours, the amount of suspension was 50 ml. Removal of chemical impurities ranged from 90 to 100%. Comparative data is aimed at identifying a faster catalyst for ferrite formation, as well as removing impurities to the maximum permissible concentration. Experimental data are aimed at reducing the environmental load of water bodies into which wastewater is discharged.
About the Authors
M. A. DenisovaRussian Federation
Denisova Maria Alekseevna, Ph.D. in Engineering Sciences, Associate Professor of the Department of Applied Geodesy, Natural Development and Water Use
Russian Federation, 40002, Volgograd, Universitetskiy prospect, 26
A. S. Ovchinnikov
Russian Federation
Ovchinnikov Aleksey Semenovich, Doctor of Agricultural Sciences, Academician of the Russian Academy of Sciences, professor head of the department of “Applied geodesy, environmental management and water use”
Russian Federation, 40002, Volgograd, Universitetskiy prospect, 26
V. S. Bocharnikov
Russian Federation
Bocharnikov Viktor Sergeevich, Doctor of Engineering Sciences, Professor of the Department of Applied Geodesy, Natural Development and Water Use
Russian Federation, 40002, Volgograd, Universitetskiy prospect, 26
O. V. Bocharnikova
Russian Federation
Bocharnikova Olesya Vladimirovna, Doctor of Engineering Sciences, Professor of the Department of Applied Geodesy, Natural Development and Water Use
Russian Federation, 40002, Volgograd, Universitetskiy prospect, 26
O. V. Kozinskaya
Russian Federation
Kozinskaya Olga Vladimirovna, Candidate of Agricultural Sciences, Associate Professor of the Department of Applied Geodesy, Environmental Management and Water Use
Russian Federation, 40002, Volgograd, Universitetskiy prospect, 26
E. V. Pustovalov
Russian Federation
Pustovalov Evgeniy Vasilievich, Candidate of Agricultural Sciences, Associate Professor of the Department of Applied Geodesy, Environmental Management and Water Use
Russian Federation, 40002, Volgograd, Universitetskiy prospect, 26
References
1. Rybalova O., Artemiev S., Sarapina M., Tsymbal B., Bakhareva A., Shestopalov O., Filenko O. Development of methods for estimating the environmental risk of degradation of the surface water state. Eastern-European Journal of Enterprise Technologies. 2018. № 2 (10-92). Pp. 4-17.
2. Ovchinnikov A. S., Bocharnikova O. V., Bocharnikov V. S. Evaluation of profitability of vegetable production in the Lower Volga region. Proc. of the Lower Volga Agro-University Complex: science and higher professional education 2007. No 1 (5). Pp. 49-53.
3. Ovchinnikov A. S., Bocharnikov V. S. New technical solutions to increase the efficiency of resource-saving methods of irrigation. Proc. of the Lower Volga Agro-University Complex: science and higher professional education. 2012. No 1 (25). Pp. 119-124.
4. Myrzalieva S. K., Pratama G. N. I. P., Khamidulla A. G. Wastewater treatment using natural zeolite materials. Integrated utilization of mineral raw materials. 2021. No 2 (317). Pp. 64-68.
5. Bocharnikova O. V., Denisova M. A., Bocharnikov V. S. Technology of preparation of natural waters for irrigation. IOP Conference Series: Earth and Environmental Science. Moscow, 2020. P. 012033.
6. Matsak A., Tsytlishvili K. Using different filter media of stormwater treatment performance. Norwegian Journal of development of the International Science. 2018. V. 1 (20). Pp. 19-22.
7. Ovchinnikov A. S., Loboyko V. F., Bocharnikov V. S., et al. State of the small rivers of the Volga basin within the lower Volga. IOP Conference Series: Earth and Environmental Science: The proceedings of the conference AgroCON-2019. Kurgan: IOP Publishing Ltd, 2019. V. 341. P. 012107.
8. Bocharnikov V. S., Meshcheryakov M. P., Denisova M. A. Study of the sorption properties of sorbents using ferrite reagents for wastewater treatment. Proc. of the Lower Volga Agro-University Complex: science and higher professional education. 2019. No 1 (53). Pp. 242-248.
9. Fedotova Yu. V., Spitsyn A. A. Treatment of wastewater from forest chemical industries. Eurasian Union of Scientists. 2019. No 12-5 (69). Pp. 46-51.
10. Smolyanichenko A. S., Yakovleva E. V. Optimization of the process of industrial wastewater treatment by disaggregation of phase-dispersed contaminants. Siberian Journal of Life Sciences and Agriculture. 2022. V. 14. No 6. P. 34-50.
11. Hajiyeva S. R., Shamilov N. T., Bayramov G. I., Rakida N. M. Ecology effective treatment of industrial wastewater formed in the oil-producing industry by coagulation method. Azerbaijan Chemical Journal. 2021. № 3. Pp. 63-66.
12. Kazeminejadfard F., Hojjati M. R. 2019 Preparation of superabsorbent composite based on acrylic acid-hydroxypropyldistarch phosphate and clinoptilolite for agricultural applications. Applied Polymer Science. 2019. V. 136 (16). 4736.
13. Kochetov G., Prikhna T., Kovalchuk O., Samchenko D. Research of the treatment of depleted nickel-plating electrolytes by the ferritization method. Eastern-European J. of Enterprise Technologies. 2018. V. 3. Pp. 52–60.
14. Kundenok S. B., Kovalenko Yu. A. Reagent purification of various types of wastewater using a three-component composition. Bulletin of the Engineering School of the Far Eastern Federal University. 2021. No 1 (46). Pp. 96-105.
15. Fadeev A. B., Kruchinina N. E., Zaitseva A. D. Treatment of wastewater from copper complex compounds Advances in chemistry and chemical technology. 2019. V. 33. No 5 (215). Pp. 93-95.
Review
For citations:
Denisova M.A., Ovchinnikov A.S., Bocharnikov V.S., Bocharnikova O.V., Kozinskaya O.V., Pustovalov E.V. Comparative evaluation of a reagent based on various сatalysts used for wastewater treatment. Title in english. 2023;(4 (72)):500-507. (In Russ.) https://doi.org/10.32786/2071-9485-2023-04-50